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Faraday-efficiency effect
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Faraday-efficiency effect : ウィキペディア英語版
Faraday-efficiency effect
The Faraday-efficiency effect refers to the potential for misinterpretation of data from experiments in electrochemistry through failure to take into account a Faraday efficiency of less than 100 per cent.
==Assumption about efficiency==
Until recent decades it was common to assume that the release of hydrogen and oxygen gas during electrolysis of water has always a Faraday efficiency of 100%. Pons and Fleischmann, and other investigators who reported the finding of anomalous excess heat in electrolytic cells,〔http://www.chem.au.dk/~db/fusion/Papers〕 all relied on this popular assumption. No one bothered to measure the Faraday efficiency in their cells during the experiments. Many publications reporting the finding of excess heat included an explicit statement like: "The Faraday efficiency is assumed to be unity." Even if not explicitly stated so, these publications included this assumption implicitly in the formulas used to calculate the cells' energy balance.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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